Gọi x, y là số mol của C và S, ta có:

\(C+O_2\rightarrow CO_2\)

x       x            x

\(S+O_2\rightarrow SO_2\)

y       y          y

\(\Rightarrow\left\{{}\begin{matrix}x+y=\dfrac{4,48}{22,4}=0,2\\12x+32y=4,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.mol\)

\(\Rightarrow m_{hh}=0,1.44+0,1.64=10,8g\)

a, \(CH_4+2O_2\underrightarrow{^{t^o}}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{^{t^o}}2CO_2+2H_2O\)

b, Gọi: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)

Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y=\dfrac{15,68}{22,4}=0,7\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=-0,1\\y=0,3\end{matrix}\right.\)

Đến đây thì ra số mol âm, bạn xem lại đề nhé.

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a          2a          a            a

\(FeS+2HCl\rightarrow FeCl_2+H_2S\uparrow\)

b            2b            b            b

\(n_{HCl}=\dfrac{400\times7.3}{100\times36.5}=0.8mol\)

\(n_X=\dfrac{4.48}{22.4}=0.2mol\)

\(M_X=2\times9=18\Leftrightarrow\dfrac{2a+34b}{a+b}=18\)

Ta có: \(\left\{{}\begin{matrix}a+b=0.2\\\dfrac{2a+34b}{a+b}=18\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a+b=0.2\\2a+34b=3.6\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.1\\b=0.1\end{matrix}\right.\)

a. \(\%V_{H_2}=\dfrac{0.1\times22.4\times100}{4.48}=50\%\)

\(\%V_{H_2S}=100-50=50\%\)

b. \(a=0.1\times56+0.1\times88=14.4g\)

\(\%m_{Fe}=\dfrac{0.1\times56}{14.4}\times100=38.8\%\)

\(\%m_{FeS}=100-38.8=61.2\%\)

c. m dung dịch sau phản ứng\(=14.4+400-0.1\times2-0.1\times34=410.8g\)

nHCl phản ứng\(=2\times0.1+2\times0.1=0.4mol\)

nHCl dư = 0.8 - 0.4 = 0.4 mol

\(C\%_{HCldu}=\dfrac{0.4\times36.5\times100}{410.8}=3.55\%\)

\(C\%_{FeCl_2}=\dfrac{0.2\times127\times100}{410.8}=6.18\%\)

n hh=\(\dfrac{4,48}{22,4}\)=0,2 mol

=>n O2=n hh=0,2 mol

=>VO2=0,2.22,4=4,48l

\(n_B=\dfrac{4,48}{22,4}=0,2mol\)

\(C+O_2\underrightarrow{t^o}CO_2\)

\(S+O_2\underrightarrow{t^o}SO_2\)

\(\Rightarrow n_B=\Sigma n_{O_2}=0,2mol\)

\(\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)

nSO2 + nCO2 = 4,48/22,4 = 0,2 (mol)

PTHH: 

S + O2 -> (t°) SO2

C + O2 -> (t°) CO2

Từ PTHH => nO2 (sử dụng) = nCO2 + nSO2 = 0,2 (mol)

=> VO2 = 0,2 . 22,4 = 4,48 (l)

1)

Coi \(n_X = 1(mol)\)

Gọi : \(n_{CO_2} = a(mol) ; n_{N_2} = b(mol)\)

Ta có :

\(n_X = a + b = 1(mol)\\ m_X = 44a + 28b = 1.1,225.32(gam)\\ \Rightarrow a = 0,7 ; b = 0,3\)

Vậy :

\(\%V_{CO_2} = \dfrac{0,7}{1}.100\% = 70\%\\ \%V_{N_2} = 100\% - 70\% = 30\%\)

2)

\(n_X = \dfrac{1}{22,4}(mol)\\ \Rightarrow m_X = n.M = \dfrac{1}{22,4}.1,225.32 = 1,75(gam)\)

a. \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

     a          2a      a

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

  b          3b       2b

b. \(n_{O_2}=\dfrac{25.88}{22.4}=1.155mol\)

n hỗn hợp khí \(=\dfrac{11.2}{22.4}=0.5mol\)

Ta có: \(\left\{{}\begin{matrix}a+b=0.5\\2a+3b=1.155\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.345\\b=0.155\end{matrix}\right.\)

\(\%V_{CH_4}=\dfrac{0.345\times22.4\times100}{11.2}=69\%\)

\(\%V_{C_2H_4}=100-69=31\%\)

c. \(V_{CO_2}=\left(a+2b\right)\times22.4=\left(0.345+2\times0.155\right)\times22.4=14.672l\)

\(n_B=\dfrac{4,48}{22,4}=0,2mol\)

\(C+O_2\underrightarrow{t^o}CO_2\)

\(S+O_2\underrightarrow{t^o}SO_2\)

\(\Rightarrow\Sigma n_B=\Sigma n_{O_2}=0,2mol\)

\(\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)

a) C₂H₄ + Br₂ --> C₂H₄Br₂

C₂H₂ + 2Br₂ --> C₂H₂Br₄

b) Gọi số mol C₂H₄, C₂H₂ là a, b (mol)

=> a + b = \(\dfrac{1,68}{22,4}=0,075\left(mol\right)\) (1)

\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

=> a + 2b = 0,1 (2)

(1)(2) => a = 0,05 (mol); b = 0,025 (mol)

=> \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,05}{0,075}.100\%=66,67\%\\\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100\%=33,33\%\end{matrix}\right.\)

c) 
PTHH: C₂H₄ + 3O₂ --t^o--> 2CO₂ + 2H₂O

           0,05--->0,15

             2C₂H₂ + 5O₂ --t^o--> 4CO₂ + 2H₂O

            0,025-->0,0625

=> V_O2 = (0,15 + 0,0625).22,4 = 4,76 (l)

a.b.\(n_{Br_2}=\dfrac{16}{160}=0,1mol\)

\(n_{hh}=\dfrac{1,68}{22,4}=0,075mol\)

Gọi \(\left\{{}\begin{matrix}n_{C_2H_2}=x\\n_{C_2H_4}=y\end{matrix}\right.\)

\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

  x          2x                            ( mol )

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

   y           y                           ( mol )

Ta có:

\(\left\{{}\begin{matrix}22,4x+22,4y=1,68\\2x+y=0,1\end{matrix}\right.\)  \(\Leftrightarrow\left\{{}\begin{matrix}x=0,025\\y=0,05\end{matrix}\right.\)

\(\%V_{C_2H_2}=\dfrac{0,025}{0,075}.100=33,33\%\)

\(\%V_{C_2H_4}=100\%-33,33\%=66,67\%\)

c.

\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\)

 0,025    0,0625                                   ( mol )

\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)

0,05        0,15                                     ( mol )

\(V_{O_2}=\left(0,0625+0,15\right).22,4=4,76l\)